Steam reforming of methane and methanol in simulated macro. Steam methane reforming synonyms, steam methane reforming pronunciation, steam methane reforming translation, english dictionary definition of steam methane reforming. The reactor model which minimizes the gibbs free energy known as. Effect of catalytic cylinders on autothermal reforming of. Distributed hydrogen production via steam methane reforming. The hydrogen obtained from smr can be used in industrial processes and in fuel cells because of its purity. High levels of purity can be reached by employing inhouse pressure swing adsorption purification technology. Advanced modelling and optimisation of natural gas. Cfd simulation with detailed chemistry of steam reforming of. Download it once and read it on your kindle device, pc, phones or tablets. Pdf efficient production of hydrogen from natural gas steam. A new multicylinder microchamber reactor is designed on autothermal reforming of methane for hydrogen production, and its performance and thermal behavior, that is, based on the reaction mechanism, is numerically investigated by varying the cylinder radius, cylinder spacing, and cylinder layout. Runi catalyst in the combined drysteam reforming of methane. Relative activities for steam reforming of methane.
Steam reforming is endothermicthat is, heat must be supplied to the process for the reaction to proceed. In order to produce valuable syngas, industrial processes of dry reforming of methane and steam reforming of methane must be further developed. The optimum choice of operating conditions of cuznal catalysts20, mainly employed in small hydrogen plants. Thermodynamic analysis of synthesis gas and higher hydrocarbons production from methane nomenclature fugacity coefficient of the species in solution. Kjersti omdahl christensen steam reforming of methane on. More important, the cu catalyst is not active for the methanation reaction reverse reforming reaction and a methane free gas can be produced at low temperatures and at high pressures to yield full conversion to co 2, co and hydrogen. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. The steam methane reforming smr process, which produces bulk hydrogen gas from methane through catalytic reactions, is the most common commercial method for industrial hydrogen production. The main purpose of this technology is hydrogen production. Reformancesmr catalysts for steam methane reforming to. Hydrogen production with co 2 capture by coupling steam reforming of methane and chemicallooping combustion. The gproms advanced model library for fixedbed reactors aml.
Methane steam reforming is a chemical process to produce hydrogen and synthesis gas mixture by combination of steam and methane in a reformer at appropriate temperature and pressure in presence of suitable metalbased catalysts 4. Steam reforming before development of psa with a polybed psa system, the co 2 removal system and methanator become redundant. Leaving the shift reactor, the gas contains approximately 75 vol% hydrogen, together with carbon dioxide, carbon monoxide, and some unconverted methane plus nitrogen, if this was present in the. Pdf hydrogen and synthesis gas by steam and co2 reforming. During the steam methane reforming smr reaction, methane reacts with steam to form syngas, i. This is achieved in a processing device called a reformer which reacts steam at high temperature with the fossil fuel. Breaking of the cbond to the nistep on the free surface, incorporation.
An energy requirement analysis of steam reforming to dry reforming with intermediate steps of steam reduction and equivalent co 2 addition to the feed fuel for syngas generation has been done to identify condition for optimum process operation. The steam methane reforming process can be broken down into five distinct steps. Chemical reactions catalyst shape design catalyst chemistry carbon fo slideshare uses cookies to improve functionality and performance, and to provide you with relevant advertising. Advanced modelling and optimisation of natural gas reforming. Pdf steam plasma methane reforming for hydrogen production. Inside a proprietary topfired steam reformer, the feed gas and steam are then heated at pressures of 15 45 barg to generate hydrogen, carbon monoxide and carbon dioxide. Depending on the quantities of the desired products, the elements of the process can be adapted.
Johnson matthey methane and catalyst steam reforming. Fbcr was used for detailed modelling of the catalyst beds considering rigorous intraparticle mass and heat transport. The gas produced by the steam reforming reaction first passes through a shift reactor, where carbon monoxide converts to carbon dioxide and hydrogen. Runi catalyst in the combined drysteam reforming of. A major commercial route for the chemical use of methane is steam reforming.
Kg, rodenbacher chaussee 4, 63403 hanauwolfgang, germany. The first units commissioned in the 1930s were run on light hydrocarbon feedstock at atmospheric pressure l, it took until 1962 for a 15atm steam reformer to come onstream in the united kingdom using liquid hydrocarbon feedstock 24. When the water to methane ratio is 3, the conversion of methane reaches 99% at 800c with the gas hourly space velocity ghsv is 3000 h1. Its getting harder for me to meet my hydrogen or syngas.
Reform3pc steamhydrocarbon reformers simulation program. The main task of the reformer is to convert a mixture of steam and methane into a hydrogen rich mixture. Reform3pc steam hydrocarbon reforming simulation program. Hydrogen production with co2 capture by coupling steam. However, the use of dry reforming, where the two main components are transformed into syngas, does not allow the desired h2co ratio. Combined steam and co 2 reforming is one of the methods to produce syngas for different applications. A similar argument is valid for co2 reforming of natural gas. Steam reforming of natural gas wikid energy funhouse. Hydrogen is used in the industrial synthesis of ammonia and other chemicals. The steam methane reforming yields a mixture of hydrogen and carbon monoxide, as follows. The results show that larger cylinder radius can promote reforming reaction.
Kinetics of steam reforming over a nialumina catalyst. In this process, oxidation of methane provides heat that is necessary for performing the endothermic methane reforming reaction using steam. Recent developments in the partial oxidation of methane to syngas. Smr is a costeffective and energy efficient way of producing hydrogen. Johnson matthey process technologies is a leader in reforming technology for the industrial production of hydrogen, methanol and ammonia to the chemicals and oil and gas sectors. Steam reforming of methane is a vital unit operation in the manufacture of synthesis gas or syngas. Use features like bookmarks, note taking and highlighting while reading production of synthesis gas by steam methane reforming.
Steam reforming of methane in a synthesis gas from biomass. Jul 28, 20 steam reforming the basics of reforming, shapes and carbon. Steam reforming of methane over a commercially available, nickelalumina catalyst was experimentally studied. This technology enables the capture of the methane value in the vicinity of pointofuse applications and natural gas pointofextraction gas to liquid systems.
Methane steam reforming, natural gas, h ydrogen, aspen plus. The methane conversion to synthesis gas mixture of co and h 2 can be realized by different processes like the methane steam reforming msr with h 2 o 1234, dry methane reforming with. Experiments were carried out varying the steam to methane ratio in the feed gas from 1 to 10 and. Gt o standard gibbs free energy change at temperature t, kj. Steam reforming is a method for producing hydrogen, carbon monoxide, or other useful products from hydrocarbon fuels such as natural gas. Steam methane reforming hydrogen production air liquide. Sulfur deactivation effects on catalytic steam reforming of. Efficient production of hydrogen from natural gas steam reforming in palladium membrane reactor article pdf available in applied catalysis b environmental 84. For more than 40 years the catalyzed hydroearbon steam reforming reaction has been of commercial value. Cfd simulation with detailed chemistry of steam reforming of methane for hydrogen production in an integrated microreactor. Many research and development programs are investigating the development of steam methane reforming technologies to enable the transition to sustainable energy, because it is. Methane steam reforming an overview sciencedirect topics. Catalytic reforming of methane in the presence of co2.
Figures 2 and 3 show examples of curves of total methane conversion and of conversion of methane into c02 vs. Sulfur, on the other hand, which is incorporated in the biomass structure, is released into the product gas during gasification as. Life cycle assessment of simulated hydrogen production by methane steam reforming article pdf available in australian journal of basic and applied sciences 111. For this purpose, methane was used the starting point and building block for the progressive understanding of reforming of complex hydrocarbons. Methane steam reforming in laboratory scale farinha, j. The direct oxidation of methane to methanol or formaldehyde has been a dream. Dry reforming is a very interesting process for synthesis gas generation from ch4 and co2 but suffers from low hydrogen yields due to. A general industrialscale smr process can be described by. In its simplest form, the steam methane reforming process for pure. Kinetics, catalysis and mechanism of methane steam reforming. Leaving the shift reactor, the gas contains approximately 75 vol% hydrogen, with carbon dioxide, carbon monoxide and some unconverted methane plus nitrogen if this was present in the feed to the. The reaction is strongly endothermic consumes heat. Reform3pc is a rating program for the firebox sections of steammethane reformer furnaces, which are used in hydrogen, ammonia and oxoalcohol production.
A possible alternative to conventional steam reforming of methane is the autothermal reforming where the exothermic partial oxidation of methane is used as heat source for the reforming reaction. In this process ch 4, h 2 o and o 2 are fed together to an adiabatic reactor where both partial oxidation and reforming of methane happen. Abstract steam reforming of methane is the main industrial route to produce hydrogen and synthesis gas a mixture of hydrogen and carbon monoxide syngas, or synthesis gas, is a fuel gas mixture. The hydrogen produced contains less than 10 ppmv of carbon oxides, but can achieve only a hydrogen concentration between 92 and 97 vol% depending on the severity of the reforming reaction. Cp o standard heat capacity at constant pressure, j. Natural gas is a fuel consisting of methane, ethane, carbon dioxide, h 2s, and trace amounts of. For this reason, the addition of water is proposed. A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst.
Johnson matthey methane and catalyst steam reforming milestones. Steam methane reforming is the most widely used process for the generation of hydrogen. The reactor employed for the study was made of 7 mm i. Redefining steam methane reformer performance in hydrogen. Dry reforming of methane eq 4 uses carbon dioxide as a feedstock rather than the water used in steam reforming eq 5, and generates syngas as. Then, the ratio of fuel gas to reforming gas is adjusted by varying the flow rate of fuel gas.
Its use for syngas production with a h2co ratio close to two would have huge environmental, social and economic impact in the actual energetic scenario. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane reforming smr. Steam reforming of methane using nibased monolith catalyst. Abstract catalytic dry reforming under industrially relevant conditions of high pressures and high temperatures poses severe challenges. Methane steam reforming, methanation and watergas shift. Water enters the furnace, producing steam at a very high temperature.
Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states. Sulfur deactivation effects on catalytic steam reforming of methane produced by biomass gasification parham 2sadooghi1, reinhard rauch 1,2vienna university of technology getreidemarkt 9166 vienna 1060 austria, email. The steam methane reforming process the steam methane reforming process can be used industrially to produce hydrogen, carbon monoxide and their mixtures. Selective separation of hydrogen for optimum conversion. On the catalytic aspects of steammethane reforming a literature. Proceedings of the 4th international gas processing symposium, 2015. Steam methane reforming syngas production air liquide. The experimental study has been done in a plug flow reactor under a near atmospheric pressure 1. Steam reforming of natural gas sometimes referred to as steam methane reforming smr is the most common method of producing commercial bulk hydrogen.
Production of synthesis gas by steam methane reforming. Introduction the steam methane reforming process is the most widespread method for the hydrogen production. Percentage of hydrogen in the reforming product gases is about 75% and the performance of this catalyst is stable. An experimental and modelling study of the pyrolysis and of the steam reforming of methane in mixtures representative of a gas produced from biomass gasification has been performed. Cfd simulation with detailed chemistry of steam reforming. Use of an ironbased waste product as oxygen carrier burning a psa tail gas.
Steam and dry co2 reforming of methane, ethanol, methanol, pyrolysis oil, and other organics in thermal plasma generated in the world unique water stabilized plasma torch is studied both. The advantages of distributed hydrogen production are the production unit can be located at the consumer refueling site, the unit capacity can be tailored to the sites fueling requirements, and this approach eliminates the need for an extensive hydrogen delivery infrastructure. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. Distributed production of hydrogen from natural gas utilizes small scale steam methane reforming technology. Introduction an efficient and reliable way to produce hydrogen gas. It simulates most reforming furnace types such as up, down, or side fired rectangular and cylindrical types, as well as terrace wall. An impact of the presence of the higher hydrocarbons on methane conversion in steam reforming of natural gas is found. Steam reforming in the pure gas phase occurs only above 6008c and the product spectrum differs from that of catalytic conversion. Authors personal copy steam reforming of methane, ethane, propane, butane, and natural gas over a rhodiumbased catalyst benjamin t. To support the interpretation of the experimental results obtained from two laboratoryscale reactors, one working in the steam methane reforming smr mode, and the other in the co2 hydrogenation. This is largely due to its cost effectivness in obtaining a high level of purity in its produced hydrogen. Modeling methanol steam reforming for internal combustion engine. Jul 30, 2015 biogas is one of the main biomassenergy resources. Steam methane reforming is the most common and economical way to make hydrogen.
In steammethane reforming, methane reacts with steam under 325 bar pressure 1 bar 14. Reform3pc is a rating program for the firebox sections of steam methane reformer furnaces, which are used in hydrogen, ammonia and oxoalcohol production. Sulfur deactivation effects on catalytic steam reforming. Pdf efficient production of hydrogen from natural gas.
Chapter 4 thermodynamic analysis of synthesis gas and higher hydrocarbons production from methane introduction the utilization of ch 4 conversion to produce important chemicals, especially synthesis gas h 2 and co, provides several advantages from the environmental and energy perspectives. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane. The amount of catalyst charge in the reactor was around 0. The conventional reforming of methane is carried out thermally using water steam and oxygen. Plasmaenabled dry methane reforming is a promising technology for biogas upgrade and shows multiple benefits to.